The earliest scientific theories of the nature of light were proposed around the end of the 17th cent. In 1690, Christian Huygens proposed a theory that explained light as a wave phenomenon. However, a rival theory was offered by Sir Isaac Newton in 1704. Newton, who had discovered the visible spectrum in 1666, held that light is composed of tiny particles, or corpuscles, emitted by luminous bodies. By combining this corpuscular theory with his laws of mechanics, he was able to explain many optical phenomena.

For more than 100 years, Newton's corpuscular theory of light was favored over the wave theory, partly because of Newton's great prestige and partly because not enough experimental evidence existed to provide an adequate basis of comparison between the two theories. Finally, important experiments were done on the diffraction and interference of light by Thomas Young (1801) and A. J. Fresnel (1814-15) that could only be interpreted in terms of the wave theory. The polarization of light was still another phenomenon that could only be explained by the wave theory. Thus, in the 19th cent. the wave theory became the dominant theory of the nature of light.

The wave theory received additional support from the electromagnetic theory of James Clerk Maxwell (1864), who showed that electric and magnetic fields were propagated together and that their speed was identical with the speed of light. It thus became clear that visible light is a form of electromagnetic radiation, constituting only a small part of the electromagnetic spectrum. Maxwell's theory was confirmed experimentally with the discovery of radio waves by Heinrich Hertz in 1886.

With the acceptance of the electromagnetic theory of light, only two general problems remained. One of these was that of the luminiferous ether, a hypothetical medium suggested as the carrier of light waves, just as air or water carries sound waves. The ether was assumed to have some very unusual properties, e.g., being massless but having high elasticity. A number of experiments performed to give evidence of the ether, most notably by A. A. Michelson in 1881 and by Michelson and E. W. Morley in 1887, failed to support the ether hypothesis. With the publication of the special theory of relativity in 1905 by Albert Einstein, the ether was shown to be unnecessary to the electromagnetic theory.

The second main problem, and the more serious of the two, was the explanation of various phenomena, such as the photoelectric effect, that involved the interaction of light with matter. Again the solution to the problem was proposed by Einstein, also in 1905. Einstein extended the quantum theory of thermal radiation proposed by Max Planck in 1900 to cover not only vibrations of the source of radiation but also vibrations of the radiation itself. He thus suggested that light, and other forms of electromagnetic radiation as well, travel as tiny bundles of energy called light quanta, or photons. The energy of each photon is directly proportional to its frequency.

With the development of the quantum theory of atomic and molecular structure by Niels Bohr and others, it became apparent that light and other forms of electromagnetic radiation are emitted and absorbed in connection with energy transitions of the particles of the substance radiating or absorbing the light. In these processes, the quantum, or particle, nature of light is more important than its wave nature. When the transmission of light is under consideration, however, the wave nature dominates over the particle nature. In 1924, Louis de Broglie showed that an analogous picture holds for particle behavior, with moving particles having certain wavelike properties that govern their motion, so that there exists a complementarity between particles and waves known as particle-wave duality (see also complementarity principle). The quantum theory of light has successfully explained all aspects of the behavior of light.